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The research group demonstrated that an axial-to-equatorial reorientation of the substrate hydroxylate induces cleavage of the O–O bond prior to the oxygenation reaction, resulting in the generation of bis(μ-oxo)-dicopper(III), which has an absorption peak at about 400 nm because of the oxide-to-Cu(III) charge transfer transition [35,36,39]
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99 PharaohG.OwenD.YeganehA.PremkumarP.FarleyJ.BhaskaranS.et al (2020)
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